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Giorgio Mattana

PrintUp Institute

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Giorgio Mattana | PrintUp Institute: What will it take to scale printed organic thermoelectrics from microvolts to milliwatts?

00:13:13 - 00:15:35

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What will it take to scale printed organic thermoelectrics from microvolts to milliwatts?

Scaling printed organic thermoelectric generators to deliver milliwatt-level power for wearable devices requires a combination of geometric integration and material-level optimization. Structurally, connecting multiple miniature generators in series raises the cumulative output voltage to a functional level suitable for microelectronics.

On a materials level, researchers must target a one-order-of-magnitude increase in electrical conductivity through controlled doping and advanced deposition techniques that optimize thin-film morphology. Additionally, the Seebeck coefficient needs a two-order-of-magnitude improvement, which is being explored via organic-inorganic hybrid composites.

By mixing organic matrices with tiny fractions of high-performing inorganic semiconductors, developers can combine the structural flexibility and printability of organics with the superior electronic properties of inorganic systems.

In this short video, you can learn:
* The geometric scaling strategy of connecting organic generators in series for higher voltage.
* The specific physical and electrical performance targets needed for milliwat-level power.
* How hybrid organic-inorganic materials can bridge the performance gap in flexible thermoelectric devices.

📋 Clip Abstract: This clip outlines the physical, chemical, and structural strategies needed to boost the power output of printed organic thermoelectric generators. The speaker shares target performance metrics for Seebeck coefficients and conductivities to transition these devices into real-world applications.

#OrganicThermoelectrics, #HybridThermoelectrics, #SeebeckCoefficient, #GeometricScaling, #PrintedElectronics, #WearableElectronics

This is a highlight of the presentation:

Additive, Sustainable or 3D Electronics Innovations Day 2025

Perovskites Innovation Day 2025

04.04.2025

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00:02:53 - 00:04:22

Can flexible organic semiconductors disrupt the market for toxic, brittle thermoelectric generators?

Can flexible organic semiconductors disrupt the market for toxic, brittle thermoelectric generators?

Traditional high-performance thermoelectric generators rely almost entirely on inorganic semiconductors. While these materials show superior energy conversion efficiency, they suffer from deep-seated commercial and manufacturing bottlenecks, including high toxicity, brittleness, heavy reliance on rare elements, and expensive processing requirements.

To overcome these limitations, researchers are shifting toward organic semiconductors. These carbon-based alternatives offer mechanical flexibility, low toxicity, and ambient-condition liquid processing, making them ideal candidates for low-cost, high-throughput printing technologies like inkjet and screen printing.

While early organic thermoelectric devices required rigid substrates and complex, non-scalable processing, the advent of fully printed organic alternatives opens up new paradigms for wearable and flexible energy harvesting.

In this short video, you can learn:
* Why inorganic thermoelectric materials struggle with commercial scalability despite high efficiencies.
* The key mechanical and processing advantages of organic semiconductors over traditional options.
* How liquid-phase processing enables the deposition of active thermoelectric layers using ambient printing techniques.

📋 Clip Abstract: This clip compares traditional state-of-the-art inorganic thermoelectric materials with emerging organic semiconductors. It highlights how printed organic electronics can overcome the brittleness and high costs of traditional inorganic thermoelectrics to enable flexible energy harvesting.

#OrganicThermoelectrics, #FlexibleSemiconductors, #LiquidPhaseProcessing, #PrintedThermoelectrics, #FlexibleEnergyHarvesting, #WearableElectronics

00:06:50 - 00:09:13

How do you formulate air-stable organic inks for printed P-type and N-type thermoelectric components?

How do you formulate air-stable organic inks for printed P-type and N-type thermoelectric components?

The fabrication of high-performance, printed organic thermoelectric generators requires careful solvent engineering of both P-type and N-type semiconducting inks. For the P-type layer, a commercial PEDOT:PSS ink is modified with organic polar solvents to improve both the final electrical conductivity (reaching approximately 400 S/cm) and its rheological printability.

For the historically problematic N-type layer, the team utilizes a novel polymer called PBDF, which offers excellent natural air stability. The N-type ink is formulated using DMSO as a solvent, with a small quantity of hydroquinone added to enhance both its conductivity and printability for pneumatic ink dispensing.

This formulation approach yields a printed organic thermoelectric generator that operates stably in ambient air without requiring complex encapsulation, maintaining its performance for hundreds of hours.

In this short video, you can learn:
* The ink formulation process for high-conductivity P-type PEDOT:PSS using polar solvents.
* How PBDF polymer can be formulated with DMSO and hydroquinone for stable N-type inks.
* The role of pneumatic ink dispensing in fabricating stable, unencapsulated organic thermoelectric devices.

📋 Clip Abstract: The speaker details the specific chemical formulations and deposition methods used to create P-type and N-type organic thermoelectric inks. He explains how these modifications lead to a device that is mechanically stable and highly conductive under ambient conditions.

#OrganicThermoelectrics, #PedotPss, #PbdfPolymer, #PneumaticDispensing, #PrintedElectronics, #EnergyHarvesting

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