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John Doricko

Quantum Solutions

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John Doricko | Quantum Solutions: Can spin-coated quantum dots replace epitaxial III-V semiconductors on CMOS wafers?

00:08:01.600 - 00:09:39.900

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Can spin-coated quantum dots replace epitaxial III-V semiconductors on CMOS wafers?

Colloidal quantum dot (CQD) technology introduces a disruptive manufacturing paradigm by replacing expensive epitaxial growth with solution-processed materials. By utilizing 1 to 20 nanometer sized particles suspended in a solution or powder form, manufacturers can deposit the active photo-absorbing layer directly onto CMOS readout integrated circuits (ROICs). This spin-coating approach leverages standard silicon fab infrastructure, bypassing the need for complex and yield-limiting wafer bonding.

The complete device architecture consists of a carefully engineered thin-film stack deposited directly onto the silicon substrate. This stack integrates an electron transport layer (ETL), the active quantum dot photo-absorbing layer, and a hole transport layer (HTL) to facilitate efficient charge carrier extraction. This direct integration on the ROIC enables a monolithic sensor design with exceptionally fine pixel pitches.

By moving to a monolithic CQD-on-silicon architecture, the cost of SWIR sensors can be reduced by several orders of magnitude while simultaneously driving resolution up by 10x or more. This capability unlocks the high-volume production of billions of SWIR-sensing units annually, making the technology viable for mainstream mobile, consumer, and industrial cameras.

In this short video, you can learn:
* How colloidal quantum dots enable monolithic integration directly onto CMOS Readout ICs (ROICs).
* The multi-layer stack architecture of a quantum dot SWIR sensor, including ETL and HTL designs.
* How solution-based processing like spin-coating bypasses traditional semiconductor epitaxial bottlenecks.

📋 **Clip Abstract** Solution-processed colloidal quantum dots offer a path to high-volume SWIR sensing by eliminating legacy epitaxial growth. This clip details the monolithic thin-film stack architecture and spin-coating deposition processes used to build CQD sensors directly on CMOS.

#ColloidalQuantumDots, #MonolithicIntegration, #SolutionProcessedSemiconductors, #CMOSROIC, #SWIRImaging, #InfraredPhotodetectors

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00:06:20.700 - 00:07:59.600

Why has shortwave infrared imaging remained locked behind a $10,000 paywall?

Why has shortwave infrared imaging remained locked behind a $10,000 paywall?

The primary obstacle to the widespread adoption of shortwave infrared (SWIR) and mid-wave infrared (MWIR) imaging lies in the material science of traditional detectors. Technologies relying on indium gallium arsenide (InGaAs) and mercury cadmium telluride (MCT) require complex epitaxial growth processes that are fundamentally incompatible with large-area silicon substrates. This incompatibility limits wafer size, severely constrains manufacturing yields, and keeps sensor costs prohibitively high.

Beyond manufacturing complexity, these exotic III-V and II-VI semiconductor systems impose steep price penalties, with typical InGaAs sensors ranging from $5,000 to $10,000, and MWIR systems costing up to ten times more. This high-cost structure restricts SWIR imaging to niche military, scientific, and high-end industrial applications, preventing its integration into mass-market consumer electronics.

Furthermore, traditional hybridization methods like indium bump bonding restrict the pixel pitch and resolution of these sensors. Consequently, most commercially available InGaAs and MCT cameras are capped at sub-megapixel resolutions, failing to meet the high-definition imaging standards demanded by modern computer vision, consumer, and automotive platforms.

In this short video, you can learn:
* Why exotic materials like InGaAs and MCT limit the scalability of infrared sensors.
* The manufacturing and yield bottlenecks that keep SWIR sensor costs in the thousands of dollars.
* Why traditional infrared detectors struggle to achieve resolutions beyond one megapixel.

📋 **Clip Abstract** Traditional SWIR and MWIR sensors are constrained by the high cost and complexity of exotic materials like InGaAs and MCT, which cannot be easily scaled on silicon. This technical clip outlines the yield, cost, and resolution limitations of legacy infrared detectors.

#SWIRImaging, #InGaAs, #IndiumBumpBonding, #EpitaxialGrowth, #Optoelectronics, #MachineVision

00:11:06.600 - 00:12:40.300

What prevents germanium-on-silicon from defeating colloidal quantum dots in the SWIR race?

What prevents germanium-on-silicon from defeating colloidal quantum dots in the SWIR race?

When evaluating alternative SWIR imaging pathways, colloidal quantum dots (CQDs) show significant performance advantages over both legacy InGaAs and emerging germanium-on-silicon (Ge-on-Si) platforms. While Ge-on-Si has long been researched as a silicon-compatible SWIR alternative, it continues to suffer from exceptionally high dark currents due to lattice mismatch defects. This high noise floor degrades image quality, keeping Ge-on-Si largely confined to R&D labs while CQD technology advances to commercial production.

In terms of optoelectronic performance, CQD sensors developed in partnership with imec have demonstrated quantum efficiencies (QE) reaching up to 75%, directly rivaling established InGaAs detectors. Moreover, CQD sensors offer an incredibly broad spectral response, covering a wide range from 350 nm up to 2500 nm, far surpassing the 940 nm cutoff of standard silicon CMOS.

The commercial roadmap for CQD SWIR sensors is structured around distinct application phases dictated by reliability and testing requirements. Machine vision and industrial sorting are already adopting CQD cameras, with consumer smartphone, AR/VR, and metaverse sensing close behind. Automotive LiDAR and ADAS integration represents the final phase, requiring several more years of rigorous high-temperature qualification and reliability screening.

In this short video, you can learn:
* The key differences in quantum efficiency and spectral range between CQD, InGaAs, and Silicon CMOS sensors.
* Why high dark current challenges keep germanium-on-silicon sensors from entering high-volume production.
* The commercial roadmap and qualification barriers for CQD integration across industrial, consumer, and automotive markets.

📋 **Clip Abstract** Colloidal quantum dot sensors offer high quantum efficiencies of up to 75% and broad spectral ranges while bypassing the dark current issues of Ge-on-Si. This clip explores the performance comparisons and commercial roadmaps for emerging SWIR technology.

#ColloidalQuantumDots, #GermaniumOnSilicon, #SWIRSensors, #CMOSImageSensors, #Optoelectronics, #MachineVision

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